Above is my hex chart for my Caio markers. If you're really observant you may have spotted my two small errors. I wasn't willing to color my chart all over again, so I drew a couple small arrows to show notate the colors I transposed. Ok, housekeeping out of the way, on with the discussion.
I use my hex chart as more of a color wheel than I do for color selection. I often start with colors in mind and select colors from my swatch book, but when I want to blend something a bit more unusual or if I use a marker that I don't have a "blending buddy" for I turn to the hex chart. For example one of my favorite blends is B99 with BG09. These are both deep dark shades and they create a stunning dark blend. I also use BG72 and G21 together for leaves, which creates a shade that reminds me of eucalyptus. These are both colors I wouldn't have blended together on my own. There is an advantage to being able to see all the shades laid out on one sheet, it opens a lot of possibilities.
The other advantage of hex chat is that it helps me see which colors I have can be swapped in for similar colors I may not have. If you look at the chart above you'll see that B29, B28, and B18 at the bottom left of the chart are nearly identical. Do I need all three of those? No. Any of those shades could be interchanged in a blend to get a similar result in your coloring.
Regardless of how you plan to use the hex chart or which style of Copics you use, I think this is a valuable tool.
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